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A Hydration Shell-Based Thermodynamic Model for Aqueous Two-Phase Systems

✍ Scribed by Pedro De Alcântara; Pessôa Filho; Rahoma S. Mohamed


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
325 KB
Volume
82
Category
Article
ISSN
0008-4034

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✍ Toshiaki Hino; John M. Prausnitz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 2 views

A lattice model is presented to compute salt-induced liquid-liquid phase separation in aqueous polymer solutions. The Gibbs energy of mixing contains an electrostatic contribution given by Pitzer's extension of the Debye-Hu ¨ckel function, and the extended Flory-Huggins theory that uses empirical fu