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A Homo Diels—Alder Approach to Bicyclo[4.2.1]nonanes.

✍ Scribed by Bin Ma; John K. Snyder

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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## Abstract A series of __cis__‐α,γ‐difunctionalized five‐membered cyclic β‐oxo esters have been chemo‐, regio‐ and diastereoselectively prepared through an efficient domino anionic ring‐cleavage/ring‐reconstitution/alkylation sequence including a 1,3‐shift of the ester group. These unsaturated sub