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A highly stereoselective total synthesis of the natural enantiomer of olivin

✍ Scribed by Roush, William R.; Michaelides, Michael R.; Tai, Dar Fu; Chong, Wesley K. M.

Book ID
125899592
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
370 KB
Volume
109
Category
Article
ISSN
0002-7863

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Stereoselective Total Synthesis of Natur
Stereoselective Total Synthesis of Natural (S)-Bakuchiol and Its Enantiomer
✍ Xiao-Long Du; Hong-Li Chen; Hui-Jin Feng; Yuan-Chao Li πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 German βš– 233 KB

## Abstract A practical stereoselective synthesis of (__S__)‐bakuchiol (**1**) and its enantiomer is reported. The important intermediate, (__R__)‐configured __Ξ²__‐siloxy aldehyde **5**, was obtained in three steps from the easily available material geraniol (**2**) __via__ the key step of __Yamamo