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A highly stereoselective synthesis ofE-11-hexadecen-1-ol acetate: Puretrans pheromones from acylsilane/ylide chemistry

โœ Scribed by John A. Soderquist; Charles L. Anderson


Book ID
103401101
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
180 KB
Volume
29
Category
Article
ISSN
0040-4039

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A highly stereoselective synthesis of Z-
โœ John A. Soderquist; Charles L. Anderson ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 425 KB

The reaction. h the presence of soluble lithium salts, of non-stabllfzed ylides at low temperature with altphatic derbatbes of acyManes g&s moderate to goad 137-82%) yields of Z-1.Pclisubstituted vin&~s trt exdlent I >96% 1 tmnerlc pwtttes for normal alkyl derbatbes. Impllcatfons of these results on