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A Highly Stereoselective Addition of the Anion Derived from α-Diazoacetamide to Aromatic N-Tosylimines.

✍ Scribed by Yonghua Zhao; Zhihua Ma; Xiaomei Zhang; Yaping Zou; Xianglin Jin; Jianbo Wang

Publisher
John Wiley and Sons
Year
2005
Weight
28 KB
Volume
36
Category
Article
ISSN
0931-7597

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A Highly Stereoselective Addition of the
A Highly Stereoselective Addition of the Anion Derived from α-Diazoacetamide to Aromatic N-Tosylimines
✍ Yonghua Zhao; Zhihua Ma; Xiaomei Zhang; Yaping Zou; Xianglin Jin; Jianbo Wang 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB

a-Diazocarbonyl compounds have found wide application in organic synthesis as a result of their diverse reactivities. [1] The previous research activities in this area have mostly concentrated on the transition metal complex catalyzed diazo decompositions, which generate metal-carbene intermediates.