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A Highly Sensitive and Selective Assay for Cysteine Using the Chemiluminescence Reaction of Luminol and Hydrogen Peroxide

✍ Scribed by Li, Yongxin ;Zhu, Changqin ;Wang, Lun

Publisher: Springer-Verlag
Year: 2005
Weight: 127 KB
Volume: 150
Category: Article
ISSN: 0344-838X
DOI: 10.1007/s00604-005-0317-8

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## Abstract A mechanism for the oxidation of cysteine by hydrogen peroxide has been proposed by Luo et al. (__J Pharm Sci__, 2005, 94, 304–316): rapid equilibrium to form cysteinate (CS^−^), followed by irreversible oxidation of CS^−^ by H~2~O~2~ to give cysteine sulfenic acid (CSOH), and nucleophi