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A highly selective method for the synthesis of symmetrical trisubstituted pyridines using transition and non-transition metal salts

✍ Scribed by F. A. Selimov; O. G. Ruttan; U. M. Dzhemilev


Book ID
112444530
Publisher
Springer
Year
1986
Tongue
English
Weight
263 KB
Volume
35
Category
Article
ISSN
1573-9171

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**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre