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A highly selective chemosensor for mercury(II) cations based on cyclometalated iridium(III) complex

✍ Scribed by Tong, Bihai; Mei, Qunbo; Lu, Mangeng


Book ID
117996248
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
482 KB
Volume
391
Category
Article
ISSN
0020-1693

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A novel ligand 9-(4-(4-chlorophenyl)phthalazin-1-yl)-9H-carbazole (HCPC) was designed and prepared, and the corresponding tris-cyclometalated iridium(III) complex Ir(CPC) 3 was readily synthesized by the reaction of the ligand with IrCl 3 Á 3H 2 O at 80 °C for 20 h. A highly efficient organic light-