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A Highly Regio- and Stereoselective Vinylogous Horner–Wadsworth–Emmons Route to Densely Substituted 1,3-Butadienes

✍ Scribed by Sonali M. Date; Sunil K. Ghosh

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
23 KB
Volume
46
Category
Article
ISSN
0044-8249

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Sequential Double Olefination of 2-(Aryl
Sequential Double Olefination of 2-(Arylmethylidene)-2-phosphonoacetonitrile with Dimsyl Lithium and Aldehydes: A Domino Route to Densely Substituted 1,3-Butadienes
✍ Raghunath Chowdhury; Sunil K. Ghosh 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB

## Abstract An efficient and highly stereoselective synthesis of densely substituted 1,3‐dienes has been achieved which entails a sequential double olefination of 2‐(arylmethylidene)‐2‐phosphonoacetonitriles by a one‐pot domino process involving Michael addition of dimsyllithium to 2‐(arylmethylide