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A highly ordered Fe–N–C nanoarray as a non-precious oxygen-reduction catalyst for proton exchange membrane fuel cells

✍ Scribed by M. Lei; P.G. Li; L.H. Li; W.H. Tang


Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
591 KB
Volume
196
Category
Article
ISSN
0378-7753

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✦ Synopsis


A highly ordered Pt-free Fe-N-C catalyst is synthesized through a hydrogen bonding-assisted selfassembly route. The catalyst has a porous structure with an average pore size of 5.5 nm and a large surface area of 416 m 2 g -1 , making it highly active in oxygen reduction. Cells assembled with the synthesized catalyst perform significantly better than those assembled with amorphous Fe-N-C cathode catalysts. The maximum powers of cells assembled from the highly ordered and amorphous catalysts are 252 and 60 mW cm -2 , respectively.