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A Highly Enantioselective Broensted Acid Catalyzed Cascade Reaction: Organocatalytic Transfer Hydrogenation of Quinolines and Their Application in the Synthesis of Alkaloids.

โœ Scribed by Magnus Rueping; Andrey P. Antonchick; Thomas Theissmann


Publisher
John Wiley and Sons
Year
2006
Weight
26 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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Synthesis of Chiral 1,3-Diamines Derived
โœ Dr. Koichi Kodama; Kazuyuki Sugawara; Prof. Takuji Hirose ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 438 KB ๐Ÿ‘ 1 views

## Abstract In this study, 13 different chiral 1,3โ€diamines were synthesized from (โˆ’)โ€__cis__โ€2โ€benzamidocyclohexanecarboxylic acid. They were successfully applied as ligands in the Cuโ€catalyzed asymmetric Henry reaction between benzaldehyde and nitromethane. It was confirmed that the enantioselect