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A highly efficient separation of structurally similar epoxy silyl ethers by complexation chromatography on polymeric organoaluminum reagents

✍ Scribed by Shigeru Nagahara; Keiji Maruoka; Hisashi Yamamoto


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
190 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis


A variety of structurally slmllar a. I3 -dlsubstl tuted epoxy sllyl ethers can be separated cleanly by our newly developed complexatlon chromatography using polymeric monomethylal~inum reagent 2 as a statronary phase

Recently we reported the virtually complete recognltlon of sLructurally or eln;tmnically very slmllar ethers with exceptionally bulky, oxygenophlllc methylalumlnum bis(2,6-di-tert-butyl-4-methylphenoxlde)

(MAD) as a Lewis-acldlc molecular cleft based on the selective Lewrs acid-base complex formatlon L,2) The