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A highly efficient one-step synthesis of (±) dihydroactinidiolide

✍ Scribed by Thomas E. Nickson

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 184 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84278-1

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✦ Synopsis

An unprecedented reaction of a 8,y-unsaturated aldehyde (1) was discovered and has been used to synthesize (k_) dihydroactinidiolide ( 2) and (&) aeginetolide (3).

A recent report described the isolation of a phytotoxic compound from spikerush (Eleocharis w.).l

The principal toxin, dihydroactinidiolide (2),2 was shown to be a potent inhibitor of seed germination and root length elongation. Our interest in this molecule has led to a new and efficient single-step

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