A Highly Efficient and Stereocontrolled Synthesis of 2-Deoxy-1,5-thioanhydro-L-hexitols from D-Glycals in a Tandem Nucleophilic Displacement Reaction

Glycals in Organic Synthesis: A Systemat

Glycals in Organic Synthesis: A Systematic Strategy for the Preparation of Uncommon Piperidine 1,2-Dideoxy-L-azasugars and 2-Deoxy-1,5-anhydro-L-hexitols

✍ Elena Ciliberti; Roberta Galvani; Francesca Gramazio; Samantha Haddas; Francesca 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB

## Abstract A systematic synthetic strategy has been developed for producing uncommon piperidine 1,2‐dideoxy‐L‐azasugars. This method involves the formation of open intermediates such as **2**, **7**, and **10** easily by ring‐opening of D‐glycals with aqueous mercury(II) acetate/sodium borohydride