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A high yielding route to substituted piperidines via the aza-Diels–Alder reaction

✍ Scribed by Patrick D Bailey; Peter D Smith; Frederick Pederson; William Clegg; Georgina M Rosair; Simon J Teat

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
96 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

The imine Ph 2 CHN CHCO 2 Et, generated from benzhydrylamine and ethyl glyoxylate, is an excellent dienophile in aza-Diels-Alder reactions, giving diastereomerically pure cycloadducts in high yield.

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