A high yielding preparation of α-trimethylsilyloxyphosphonates by silylation of α-hydroxyphosphonates with HMDS catalyzed by iodine
✍ Scribed by Habib Firouzabadi; Nasser Iranpoor; Sara Sobhani
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 94 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A general, versatile, high yielding and convenient procedure for the immediate conversion of various a-hydroxyphosphonates to a-trimethylsilyloxyphosphonates under neutral conditions using HMDS in the presence of a catalytic amount of iodine is described.
📜 SIMILAR VOLUMES
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converted to a-ketophosphonates by zinc dichromate trihydrate in high yields and rates under solvent-free conditions.
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