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A HIGH YIELD, SELECTIVE SYNTHESIS OF 1,3,5-TRIMETHOXYBENZENE

✍ Scribed by Ji, Ya-Fei; Zong, Zhi-Min; Wei, Xan-Yong


Book ID
120345068
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
172 KB
Volume
35
Category
Article
ISSN
0030-4948

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Selective nucleophilic displacement of a
✍ P. H. M. Budzelaar; J. A. van Doorn πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 183 KB

## Abstract A methoxy group in 1,2, 3‐trimethoxybenzenes can be readily displaced by a butyl group via reaction with butyllithium in hexane. The reaction probably proceeds via an addition‐elimination mechanism. There appears to be a qualitative relation between the coefficient of the LUMO at the ce