## Tritiated (E, E )-(2-diazo-3-trifluoropropionyloxy)geranyl diphosphate (DATFP-GDP) has been used as a photolabile analogue of (E,E)-farnesyl diphosphate (E,E-FDP) for an aid in isolating enzymes utilizing E,E-FDP as a substrate. We now report an alternative method of synthesizing this probe in
A High-Yield, Enzymatic Synthesis of GDP-d-[3H]Arabinose and GDP-l-[3H]Fucose
β Scribed by Brenda J. Mengeling; Salvatore J. Turco
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 98 KB
- Volume
- 267
- Category
- Article
- ISSN
- 0003-2697
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## Abstract A simple synthesis of 5βdeoxyβLβ[5β^2^H~1~]arabinose was performed to obtain Lβ[3β²β^2^H~1~]biopterin. The reduced form of this model substance is needed to investigate the pathway of 7βsubstituted pterins in patients with primapterinuria.
Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115Β±130 Β°C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 Β΄x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6Β± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4Β± species. Similar re