A high-pressure adn low-temperature Mössbauer effect study of an iron(III) squarate complex

Thermally induced high-spin (5T2) ⇌ low-

Thermally induced high-spin (5T2) ⇌ low-spin (1A1) transitions in bis[2-(2-pyridylamino)—4-(2-pyridyl)thiazole]iron(II) complexes: a Mössbauer effect study

✍ E. König; G. Ritter; H.A. Goodwin 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc