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A high-potential mononuclear manganese(IV) complex. Synthesis, structure, and properties, including EPR spectroscopy and electrochemistry, of [Mn(HB(3,5-Me2pz)3)2] (ClO4)2 (pz = pyrazolyl)

✍ Scribed by Chan, Michael K.; Armstrong, William H.


Book ID
121437556
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
425 KB
Volume
28
Category
Article
ISSN
0020-1669

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From a solution prepared by a reaction of Mo 2 (O 2 CCH 3 ) 4 with KTp\* (Tp\*= hydridotris(3,5-dimethylpyrazolyl)borate, HB(Me 2 Pz) 3 ), in diglyme at room temperature followed by addition of excess (CH 3 ) 3 SiBr to the red solution in refluxing THF, the complexes [HB(Me 2 Pz) 3 )BH][Br 3 Mo(m-Br

Monometallic, homo- and hetero-bimetalli