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A High-Frequency and High-Field EPR Study of New Azide and Fluoride Mononuclear Mn(III) Complexes

✍ Scribed by Mantel, Claire; Hassan, Alia K.; Pécaut, Jacques; Deronzier, Alain; Collomb, Marie-Noëlle; Duboc-Toia, Carole


Book ID
119978802
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
159 KB
Volume
125
Category
Article
ISSN
0002-7863

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High-Spin Chloro Mononuclear MnIII Compl
✍ Claire Mantel; Hongyu Chen; Robert H. Crabtree; Gary W. Brudvig; Jacques Pécaut; 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB

## Abstract __The isolation, structural characterization, and electronic properties of two six‐coordinated chloromanganese (III) complexes, [Mn(terpy)(Cl)~3~] (1) and [Mn(Phterpy)(Cl)~3~] (2), are reported (terpy=2,2′:6′2′′‐terpyridine, Phterpy=4′‐phenyl‐2,2′:6′,2′′‐terpyridine). These complexes co