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A Heterobimetallic Ga/Yb-Schiff Base Complex for Catalytic Asymmetric α-Addition of Isocyanides to Aldehydes

✍ Scribed by Mihara, Hisashi; Xu, Yingjie; Shepherd, Nicholas E.; Matsunaga, Shigeki; Shibasaki, Masakatsu


Book ID
119939274
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
310 KB
Volume
131
Category
Article
ISSN
0002-7863

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## Abstract Three new chiral 3‐substituted BINOL Schiff bases and their reductive 3‐arylaminomethyl BINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active se