A Hermitean reformulation of the Born–Oppenheimer nonadiabatic coupling terms for diatomic molecules
✍ Scribed by Joachim Römelt
- Book ID
- 104581083
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 187 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0020-7608
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📜 SIMILAR VOLUMES
In the usual formulation of the close-coupled equations for the collision of two diatomic molecules, one assumes that the channel expansion forms an orthonormai set. This assumption can be invalid at small cenrer-of-mass separations. We show how one can deal with this problem while solving the close
A Dunham treatment of an effective Hamiltonian for diatomic molecules in 2 ⌺ states that includes contributions of the Born-Oppenheimer breakdown has yielded an expression for vibrational-rotational energy by an expansion in powers of (v ϩ state and k ϭ 0, 1, . . . , j. Analytic expressions for the