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A heptaruthenium carbonyl cluster: synthesis and structural characterization of [PPN][HRu7(CO)20]

✍ Scribed by Housecroft, Catherine E.; Rheingold, Arnold L.; Song, Xuejing

Book ID
126022967
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
318 KB
Volume
31
Category
Article
ISSN
0020-1669

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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an β€œelectron reservoir”. (Β© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,