Novel stereocontrolled glycosidations of 3,4-di-O-wotected olivoses and alcohols using a heterogenem~ and environmentally benign solid acid, montmoriilonite K-10, have been developed. The glycosidatlons of the 3-O-Ac-4-O-TBS-olivuse (4) and various alcohols using montmorilionite K-10 in CH2CI2 at 25
โฆ LIBER โฆ
A Glycosidation Reaction Employing Montmorillonite K-10 as Catalyst
โ Scribed by Bedell, Brooke L.; Crouch, R. David; Holden, Michael S.; Martinson, Heidi E.
- Book ID
- 121088646
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 42 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0021-9584
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Montmorillonite K-10 and KSF as Remarkable Acetylation Catalysts. -The title compounds are good catalysts for the acetylation of compounds such as (I), (IV), and (VI) but not for tertiary alcohols. The method presented has the additional advantages of mild conditions, high yield, easy separation an