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A Generalized Method for Predicting Second Virial Coefficients

✍ Scribed by Hayden, J. George; O'Connell, John P.

Book ID
111923070
Publisher
American Chemical Society
Year
1975
Weight
922 KB
Volume
14
Category
Article
ISSN
0196-4305

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## Abstract A simple modification of the Pitzer relation to calculate second virial coefficients of polar compounds is proposed. The proposed modification is based on the use of a new parameter, Ξ², which embodies both the contributions of acentricity and polarity to second virial coefficient values

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## Abstract One of the most readily available characteristics of a polymer sample is its intrinsic viscosity in a particular solvent. This datum can often be estimated reasonably from a single relative viscosity measurement. A number of theories permit the calculation of the second virial coefficie