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A generalization of the Dubinin—Radushkevich equation for the filling of heterogeneous micropore systems

✍ Scribed by H.F Stoeckli

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
147 KB
Volume
59
Category
Article
ISSN
0021-9797

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📜 SIMILAR VOLUMES

Estimation of the dimensions of micropor
Estimation of the dimensions of micropores in active carbons using the Dubinin-Radushkevich equation
✍ Brian McEnaney 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 618 KB

Decreases in the characteristic energy of the Dubinin-Radushkevich equation, E,,, are correlated with increases in micropore sizes determined by molecular probes, W,,,, using the empirical equation W, = 4.691 exp( -0.0666&J; a similar equation can also be used to correlate the more limited data rela

The enthalpies of immersion of active ca
The enthalpies of immersion of active carbons, in relation to the Dubinin theory for the volume filling of micropores
✍ H.F. Stoeckli; F. Kraehenbuehl 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 373 KB

## It is shown that an exact expression can be derived from Dubinin's theory, for the enthalpy of immersion of active carbons. It appears that for a given liquid, the specific enthalpy of immersion is a function of the characteristic energy REo of the Dubinin-Astakhov equation. The new relation is

The Dubinin theory of micropore filling
The Dubinin theory of micropore filling and the adsorption of simple molecules by active carbons over a large range of temperature
✍ H.F. Stoeckli; J.Ph. Houriet 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 466 KB

It is shown that the values of the structural constant B and of the micropore volume W, can change considerably for certain active carbons, when the adsorption of simple gases is measured over a large range of temperature. The changes are probably related to ultramicrop?rosity, present in heterogene