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A generalization of the base effect on the diastereoselective synthesis of sulfinic and phosphinic esters

✍ Scribed by Inmaculada Fernández; Noureddine Khiar; Aránzazu Roca; Abdelhak Benabra; Ana Alcudia; JoséL. Espartero; Felipe Alcudia

Book ID
104260967
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
198 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Various chinil secondary alcohols have been u~d to study the dcpcn(Icnce of the sterexx:hemicad outcome of sulfinate and phosphinalc ester synthesis on the nan=re of the base used to cataly,se the reaction. From this study it has been shown thai the achiml stercodirccting ha~ clfcct dctcrminexl in the DAG methedology is a general bchaviour in the asymmetric synlbesis of s,,llinalC and phosphinale osiers.

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