A general synthesis of isotwist-8-en-2-ones from o-(3-butenyl)phenols
โ Scribed by Tadas S. Macas; Peter Yates
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 163 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Wessely oxidation of o-(3.butenyl)phenols with lead tetraacetate _ gives 2,4-cyclohexadienone derivatives that on heating undkrgo intramolecular Diels-Alder reactions to give 3-acetoxyisotwist-8en-2-ones.
๐ SIMILAR VOLUMES
## Abstract Trichloroโsubstituted 8โoxabicyclo[3.2.1]octโ6โenโ3โones **6** and **7** are solvolysed by methanolic sodium methoxide to form the bicyclo[3.2.1] ฮฑ,ฮฑโdimethoxy ketones **13** and **14**, with preservation of one chloro substituent. In the case of **6a**, prolonged reaction time with an
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