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A general synthesis of 1-, 2-, 3-, and 4-substituted benz[a]anthracene-7,12-diones

✍ Scribed by Manning, Wayne B.; Tomaszewski, Joseph E.; Muschik, Gary M.; Sato, Ronald I.

Book ID
126798521
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
483 KB
Volume
42
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

A facile synthesis of benz[a]anthracene-
A facile synthesis of benz[a]anthracene-7,12-diones
✍ Joseph E. Tomaszewski; Wayne B. Manning; Gary M. Muschik πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 182 KB

The synthesis of the potent carcinogen 7,12-dimethylbenzCa]anthracene, DMBA, 4a and its many derivatives has been difficult in the past due to the lack of commercially available starting materials. Of the various methods available for its synthesis (l-4) , the simplest involves the addition of methy

The preparation of specifically 2H-label
The preparation of specifically 2H-labeled benz[A]anthracenes and 7,12-dimethylbenz[A]anthracenes1
✍ Richard K. Hallmark; Wayne B. Manning; Gary M. Muschik πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 French βš– 537 KB

## Abstract The 2 + 4 cycloaddition reaction of 1,4‐naphthoquinone and substituted styrenes was used to prepare 1‐, 2‐, 3‐, and 4‐bromobenz[a]anthracene‐7,12‐diones (BADs). The corresponding bromobenz[a]anthracenes (BAs) were prepared by aluminum tricyclohexoxide reduction of the diones. Lithiation