✦ LIBER ✦
A General Strategy for the Synthesis of Conjugated Polymers Based upon the Palladium-Catalysed Cross-Coupling of Grignard Reagents with Unsaturated Halides
✍ Scribed by Francesco Babudri; Donato Colangiuli; Gianluca M. Farinola; Francesco Naso
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 143 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
Palladium-catalysed cross-coupling between aromatic bis-organomagnesium reagents and aromatic dihalides has been experimentally evaluated as a general methodology for the synthesis of soluble conjugated polymers such as poly(pphenylene)s 6 and 7, poly(p-terphenylenevinylene) 8, poly-(phenylenethiophene) 9 and poly(phenylenepyridine) 10. Appropriate experimental conditions were first found in