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A general, selective synthesis of ω-hydroxyethenyl ethers

✍ Scribed by E Cabianca; F Chéry; P Rollin; A Tatibouët; O De Lucchi

Book ID
104232236
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
127 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

A general selective synthesis of b-, gand d-hydroxyethenyl ethers, a class of compounds containing two mutually reactive functionalities positioned at an interacting distance, is based on the reaction of diols with 1,2-bis-(phenylsulfonyl)ethylene (BPSE) followed by reductive elimination of the resulting b-phenylsulfonyl acetals with sodium amalgam.

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