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A General Route to α-Alkyl (E)-α,β-Unsaturated Aldehydes.

✍ Scribed by Nour Lahmar; Jamaa Aatar; Taicir Ben Ayed; Hassen Amri; Moncef Bellassoued

Publisher
John Wiley and Sons
Year
2006
Weight
25 KB
Volume
37
Category
Article
ISSN
0931-7597

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Oxidation of Aldehydes to α,β-Unsaturate
Oxidation of Aldehydes to α,β-Unsaturated Aldehydes via α-Chloroaldimines
✍ Norbert De Kimpe; Christian Stevens 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 354 KB

The oxidation of aldehydes to a@-unsaturated aldehydes has been performed by a sequence of reactions involving conversion into aldimines, chlorination at the a-position to form a-chloroaldimines, base-induced dehydrochlorination and h drol sis The four-step transformation can be executed without iso