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A General Route to Strictly Dinuclear Cu(II)/Ln(III) Complexes. Structural Determination and Magnetic Behavior of Two Cu(II)/Gd(III) Complexes

✍ Scribed by Costes, J.-P.; Dahan, F.; Dupuis, A.; Laurent, J.-P.


Book ID
119999999
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
244 KB
Volume
36
Category
Article
ISSN
0020-1669

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A Series of Trinuclear Cu II Ln III Cu I
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A series of trinuclear Cu(II)Ln(III)Cu(II) complexes with the bridging ligand 2,6-di(acetoacetyl)pyridine have been prepared by one-pot reaction with Cu(NO(3))(2).3H(2)O and Ln(NO(3))(3).nH(2)O in methanol. X-ray crystallographic studies for all the complexes indicate that two L(2)(-) ligands select