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A general protocol for the regio high yielding opening of different glycidol derivatives

✍ Scribed by Carlo Bonini; Lucia Chiummiento; Maria Teresa Lopardo; Maddalena Pullez; Françoise Colobert; Guy Solladié

Book ID
104253249
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
115 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Differently protected glycidol derivatives (with Bn, TBDPS, TBS and MPM groups) have been tested for regioselective ring opening with vinylmagnesium bromide in order to obtain useful five-carbon functionalised homoallylic alcohols. Careful choice of the reagents and experimental conditions allowed a general access to important chiral synthons for asymmetric synthesis.

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