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A general protocol for the hydroxylation of C-14 in gibberellins: synthesis of 14β-hydroxy-GA1 methyl ester

✍ Scribed by Jianping Liu; Lewis N. Mander; Anthony C. Willis

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
955 KB
Volume
54
Category
Article
ISSN
0040-4020

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A general procedure for the preparation
A general procedure for the preparation of 11β-hydroxy gibberellins: Synthesis of the methyl esters of GA35 and 11β-hydroxy-GA7
✍ Lewis N. Mander; Graham L. Patrick 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 254 KB

Hydroboration of gibberellin 9(11),16\_dienes provides good access to lla,l7-diols from which 11 P\_hydroxy gibberellins may be prepared, eg. gibberellin A35 (2) and 1 lkhydroxy gibberellin A7 (4). a new gibberellin from Ldium temulentum.