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A general method for the synthesis of 3,4-epoxy-2-methylenealkanoic acid derivatives using dianion of N-phenyl-2-(phenylsulfonylmethyl)-propenamide

✍ Scribed by Kazuhiko Tanaka; Hidemi Yoda; Aritsune Kaji


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
192 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis


A general procedure has been developed for the synthesis of 3,4-epoxy-2-methylenealkanoic acid derivatives using dianion of N-phenyl-2-(phenylsulfonylmethyl)propenamide and aldehydes.


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## Abstract magnified image Electrochemical oxidation of catechols to corresponding __o__‐quinones was successfully performed in aqueous solution by electrolysis at the controlled potentials. Quinones derived from catechols, participate in Michael addition reactions with 5‐phenyl‐1,3,4‐oxadiazole‐