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A General and Selective Copper-Catalyzed Cross-Coupling of Tertiary Grignard Reagents with Azacyclic Electrophiles

✍ Scribed by Lukas Hintermann; Li Xiao; Aurélie Labonne

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
320 KB
Volume
120
Category
Article
ISSN
0044-8249

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## Abstract The title reaction has been studied under low temperature conditions. Coupling with active substrates can be done even at dry ice temperature. Initial rate studies at −25 °C indicate that high concentrations of any reagent can lead to either complete or partial catalyst deactivation. Un