A versatile and new highly stereoselecti
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G.J.P.H Boons; G.A van der Marel; J.H van Boom
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Article
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1989
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Elsevier Science
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French
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The reaction of (phenyldimethyl)silylmethyl.magnesiu chloride with benzyl 2,3,4tri-0-benzyl-a-D-manno-hexodialdo-1,5-pyranoside affords the corresponding L-glycero-Dmanno-addition product having at C-7 the phenyldim:thylsilyl (PDMSi) group. The latter silanyl compound survived benzylation as veil as