## Abstract For Abstract see ChemInform Abstract in Full Text.
✦ LIBER ✦
A general and facile synthesis of 1,3-diaryl-4-pyrazoleacetic acid esters
✍ Scribed by David D. Xu; George T. Lee; Xinglong Jiang; Kapa Prasad; Oljan Repic; Thomas J. Blacklock
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2005
- Tongue
- English
- Weight
- 84 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
✦ Synopsis
A general synthesis of 1,3-diaryl-4-pyrazoleacetic acid esters has been realized via the condensation of a γ-carboxy ester hydrazone with the Vilsmeier reagent.
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## Abstract The pyrolysis of 1‐aroylamino‐4,5‐diphenyl‐1,2,3‐triazoles 1 yields, pressumably __via__ the 4,5‐diphenyl‐1,2,3‐triazolyl radical (2a), 2,3‐diphenyl‐2__H__‐azirine (11a) and 2‐aryl‐4,5‐diphenylimidazoles 14 as the major products. Upon irradiation 1‐benzoylamino‐4,5‐diphenyl‐1,2,3‐triazo