A gas-phase XPS study of iron cluster compounds
β Scribed by David B. Beach; James L. Hoskins; William L. Jolly; Steven P. Smit; Si Fen Xiang
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 217 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0368-2048
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The formation and stability of aqueous clusters of nitric acid were studied utilizing a free-jet expansion techmque, coupled with electron impact ionization mass spectrometry. Evidence for the onset of salvation at very small cluster srzes is presented.
Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H2SOI-H20, -53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, -67 kJ