An iteration scheme for the implicit treatment of equilibrium chemical reactions in partial equilibrium flow has previously been described (J. D. Ramshaw and A. A. Amsden, J. Comput. Phys. 59, 484 (1985); 71, 224 (1987)). Here we generalize this scheme to kinetic reactions as well as equilibrium rea
A Gas-Kinetic Scheme for Multimaterial Flows and Its Application in Chemical Reactions
β Scribed by Y.S. Lian; K. Xu
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 415 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0021-9991
No coin nor oath required. For personal study only.
β¦ Synopsis
This paper concerns the extension of the multicomponent gas-kinetic BGK-type scheme to chemical reactive flow calculations. In the kinetic model, each component satisfies its individual gas-kinetic Bhatnagar-Gross-Krook (BGK) equation, and the equilibrium states of both components are coupled in space and time due to the momentum and energy exchange in the course of particle collisions. At the same time, according to the chemical reaction rule, one component can be changed into another component with a release of energy. The reactant and product may have different ratios of specific heats. The BGK scheme basically uses the collisional Boltzmann model to mimic the numerical dissipation necessary for shock capturing. The numerical dissipation is controlled by the particle collision pseudo-time Ο . In the resolved viscous calculations, there is a direct relation between the physical viscosity coefficient and the particle collision time. Many numerical test cases presented in this paper validate the gas-kinetic approach in the application of multicomponent reactive flows.
π SIMILAR VOLUMES
A kinetic method for hyperbolic-elliptic equations is presented in this paper. In the mixed type system, the coexistence of liquid and gas and the phase transition between them are described by the van der Waals-type equation of state (EOS). Because the fluid is unstable in the elliptic region, the
This paper presents an improved gas-kinetic scheme based on the Bhatnagar-Gross-Krook (BGK) model for the compressible Navier-Stokes equations. The current method extends the previous gas-kinetic Navier-Stokes solver developed by Xu and Prendergast (J. Comput. Phys. 114, 9) by (a) implementing a gen
In this work a new mass spectrometry based method for monitoring the kinetics of chemical reactions in solution is described. A stopped-flow mixing instrument is coupled to an electrospray ionization (ESI) mass spectrometer via a novel type of interface. Chemical reactions are initiated by rapid mix