𝔖 Bobbio Scriptorium
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A FREE RADICAL WAGNER-MEERWEIN REARRANGEMENT

✍ Scribed by Berson, Jerome A.; Olsen, Carl J.; Walia, Jasjit Singh


Book ID
127184205
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
272 KB
Volume
82
Category
Article
ISSN
0002-7863

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## Abstract Irradiation of the octalin‐derived sesquiterpene oxide α‐agarofuran in methanol leads to rearrangement to the perhydroazulene system, in addition to simple double‐bond migration to β‐agarofuran. This rearrangement apparently proceeds through a carbonium‐ion‐like intermediate, whereas co