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A Free Radical Method for Reduction of Cyclohexanones — Preferential Formation of Equatorial Alcohols.

✍ Scribed by Derrick L. J. Clive; Hua Cheng

Publisher
John Wiley and Sons
Year
2003
Weight
103 KB
Volume
34
Category
Article
ISSN
0931-7597

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A new, stereocontrolled synthesis of equ
A new, stereocontrolled synthesis of equatorial alcohols by the ambiphilic reduction of cyclohexanones
✍ Keiji Maruoka; Minoru Sakurai; Hisashi Yamamoto 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 217 KB

Ambiphilic reduction of cyclohexanones with methylaluminum bis(2,6-di-tert-butyl-4methylphenoxide) and tert-butylmagnesium chloride provides the corresponding equatorial alcohols with high stereoselectivity. . In connection with our recent project on the utility of ambiphilic systems in organic syn