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A Four-Carbon Unit Reagent for the Regiospecific Synthesis of 2-Alkyl-Substituted 1,3-Butadienes

โœ Scribed by Katritzky, Alan R.; Serdyuk, Larisa; Toader, Dorin; Wang, Xiaojing


Book ID
120159242
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
170 KB
Volume
64
Category
Article
ISSN
0022-3263

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1-tert-Butoxycarbonyl-1-tosyl-hydrazine
โœ Leif Grehn; Ulf Ragnarsson ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 626 KB

Catalytic hydrogenolysis of l-Boc-l-Ts-2-Z-hydrazane furnished l-Boc-l-Ts-hydrazine as a stable crystalline solid. Although its nacleophilicity is considerably suppressed in comparison with that of non-or monoacylated hydrazines, it reacted under various conditions with a representative set of keton