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A formal total synthesis of the telomerase inhibitor dictyodendrin B

✍ Scribed by Shotaro Hirao; Yuki Yoshinaga; Masatomo Iwao; Fumito Ishibashi

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
558 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

A formal synthesis of the telomerase inhibitory marine pyrrolocarbazole alkaloid dictyodendrin B is described. The key features are consecutive palladium-catalyzed cross-coupling reactions and intramolecular reductive coupling reaction to construct the pyrrolo[2,3-c]carbazole framework.

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Technology for the award of a Top Achiever Doctoral Scholarship to K.Y.T. and D.C.K.R. We are also grateful to Profs. Y. Kita and Fujioka for providing an authentic sample of 6.