The recent linear extension of the Debye-HUckel theory predicts the breakdown of the Debye-Hitickel theory at Ka= 1.2412.
A formal mathematical legalization of the “exponential” debye—hückel theory
✍ Scribed by I. Ruff
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 131 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
By hnesization of the Poisson-Bolzzmann equation in a differcat waly from that usually folloued, the neysutity of the par correlation functions of like-charged ons can be avoded The exp. "con thus obtanted for the par correlation functons yelds values very close to the exponentul Debye-Huckel (DIIX) spprovimation Since these neil palr corredatun functions leave the DH charge distribution analyticully intat. therr use does not viokale Ille electrontutrality condituon whin the DHX does
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