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A flavan-3-ol glycoside from bark of Plumeria rubra

โœ Scribed by Leonardus B.S. Kardono; Sofjan Tsauri; Kosasih Padmawinata; A. Douglas Kinghorn


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
291 KB
Volume
29
Category
Article
ISSN
0031-9422

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Oxymcrcuration of (R)-sulcatol (1) to (3R,6R)-2 was followed by its treatment with NaBH, and oxygen lo give (3S,6R)-tetra-Iiydro-2,2,6-trimethyl-2H-pyran-3-01 ( 3 4 and (3R,6R)-3n'. In thc same manner, (3R.69-3a and (3S,GS)-3a' were synthesized from ( Q I . Tetrahydro-2,2,6-trimethyl-2H-pyran-3-01