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A Fast Catalytic Asymmetric Aza-Morita–Baylis–Hillman Reaction of N-Sulfonated Imines with Methyl Vinyl Ketone in the Presence of Chiral Bifunctional Phosphane Lewis Bases

✍ Scribed by Zhi-Yu Lei; Guang-Ning Ma; Min Shi


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
120 KB
Volume
2008
Category
Article
ISSN
1434-193X

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Dendritic Chiral Phosphine Lewis Bases-C
✍ Ying-hao Liu; Min Shi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB 👁 2 views

## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (