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A Family of Mn 16 Single-Molecule Magnets from a Reductive Aggregation Route

✍ Scribed by King, Philippa; Wernsdorfer, Wolfgang; Abboud, Khalil A.; Christou, George


Book ID
120372471
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
361 KB
Volume
43
Category
Article
ISSN
0020-1669

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## Abstract Complexes [Fe~9~(X)~2~(O~2~CMe)~8~{(2‐py)~2~CO~2~}~4~] (X^βˆ’^=OH^βˆ’^ (1), N~3~^βˆ’^ (2), and NCO^βˆ’^ (3)) have been prepared by a route previously employed for the synthesis of analogous Co~9~ and Ni~9~ complexes, involving hydroxide substitution by pseudohalides (N~3~^βˆ’^, NCO^βˆ’^). As indica